Hard water marks on gutters

Is the any cleaning products that will remove hard watermarks off gutter ? Many thanks

Green scotch pads and solvent/cream cleaners sometimes get it off. But to be honest on old plastic gutters I don't bother that much as just say to the customer when finished "All done...it looks alot cleaner than before but there are some stains on their that wont come off. What do you think" Most if not all will be happy with the results as you can only do so much with old plastic.